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 <front>
  <journal-meta>
   <journal-id journal-id-type="publisher-id">Russian Journal of Earth Sciences</journal-id>
   <journal-title-group>
    <journal-title xml:lang="en">Russian Journal of Earth Sciences</journal-title>
    <trans-title-group xml:lang="ru">
     <trans-title>Russian Journal of Earth Sciences</trans-title>
    </trans-title-group>
   </journal-title-group>
   <issn publication-format="online">1681-1208</issn>
  </journal-meta>
  <article-meta>
   <article-id pub-id-type="publisher-id">46535</article-id>
   <article-id pub-id-type="doi">10.2205/2020ES000703</article-id>
   <article-categories>
    <subj-group subj-group-type="toc-heading" xml:lang="ru">
     <subject>ОРИГИНАЛЬНЫЕ СТАТЬИ</subject>
    </subj-group>
    <subj-group subj-group-type="toc-heading" xml:lang="en">
     <subject>ORIGINAL ARTICLES</subject>
    </subj-group>
    <subj-group>
     <subject>ОРИГИНАЛЬНЫЕ СТАТЬИ</subject>
    </subj-group>
   </article-categories>
   <title-group>
    <article-title xml:lang="en">Mineralogy, geochemistry and geological occurrence of supergene manganese ore mineralization in North West Province, South Africa</article-title>
    <trans-title-group xml:lang="ru">
     <trans-title>Mineralogy, geochemistry and geological occurrence of supergene manganese ore mineralization in North West Province, South Africa</trans-title>
    </trans-title-group>
   </title-group>
   <contrib-group content-type="authors">
    <contrib contrib-type="author">
     <name-alternatives>
      <name xml:lang="ru">
       <surname>Pharoe</surname>
       <given-names>Benedick Kinshasa </given-names>
      </name>
      <name xml:lang="en">
       <surname>Pharoe</surname>
       <given-names>Benedick Kinshasa </given-names>
      </name>
     </name-alternatives>
     <email>benedictpharoe1@gmail.com</email>
     <xref ref-type="aff" rid="aff-1"/>
    </contrib>
    <contrib contrib-type="author">
     <name-alternatives>
      <name xml:lang="ru">
       <surname>Evdokimov</surname>
       <given-names>A N</given-names>
      </name>
      <name xml:lang="en">
       <surname>Evdokimov</surname>
       <given-names>A N</given-names>
      </name>
     </name-alternatives>
     <xref ref-type="aff" rid="aff-2"/>
    </contrib>
    <contrib contrib-type="author">
     <name-alternatives>
      <name xml:lang="ru">
       <surname>Gembitskaya</surname>
       <given-names>I M</given-names>
      </name>
      <name xml:lang="en">
       <surname>Gembitskaya</surname>
       <given-names>I M</given-names>
      </name>
     </name-alternatives>
     <xref ref-type="aff" rid="aff-3"/>
    </contrib>
    <contrib contrib-type="author">
     <name-alternatives>
      <name xml:lang="ru">
       <surname>Baiyegunhi</surname>
       <given-names>Christopher </given-names>
      </name>
      <name xml:lang="en">
       <surname>Baiyegunhi</surname>
       <given-names>Christopher </given-names>
      </name>
     </name-alternatives>
     <xref ref-type="aff" rid="aff-4"/>
    </contrib>
    <contrib contrib-type="author">
     <name-alternatives>
      <name xml:lang="ru">
       <surname>Nxantsiya</surname>
       <given-names>Zusakhe </given-names>
      </name>
      <name xml:lang="en">
       <surname>Nxantsiya</surname>
       <given-names>Zusakhe </given-names>
      </name>
     </name-alternatives>
     <xref ref-type="aff" rid="aff-5"/>
    </contrib>
   </contrib-group>
   <aff-alternatives id="aff-1">
    <aff>
     <institution xml:lang="ru">Saint Petersburg Mining University</institution>
     <country>ru</country>
    </aff>
    <aff>
     <institution xml:lang="en">Saint Petersburg Mining University</institution>
     <country>ru</country>
    </aff>
   </aff-alternatives>
   <aff-alternatives id="aff-2">
    <aff>
     <institution xml:lang="ru">Saint Petersburg Mining University</institution>
     <country>ru</country>
    </aff>
    <aff>
     <institution xml:lang="en">Saint Petersburg Mining University</institution>
     <country>ru</country>
    </aff>
   </aff-alternatives>
   <aff-alternatives id="aff-3">
    <aff>
     <institution xml:lang="ru">Saint Petersburg Mining University</institution>
     <country>ru</country>
    </aff>
    <aff>
     <institution xml:lang="en">Saint Petersburg Mining University</institution>
     <country>ru</country>
    </aff>
   </aff-alternatives>
   <aff-alternatives id="aff-4">
    <aff>
     <institution xml:lang="ru">Department of Physics and Geology, University of Limpopo</institution>
     <country>ru</country>
    </aff>
    <aff>
     <institution xml:lang="en">Department of Physics and Geology, University of Limpopo</institution>
     <country>ru</country>
    </aff>
   </aff-alternatives>
   <aff-alternatives id="aff-5">
    <aff>
     <institution xml:lang="ru">Council for Geosciences</institution>
     <country>ru</country>
    </aff>
    <aff>
     <institution xml:lang="en">Council for Geosciences</institution>
     <country>ru</country>
    </aff>
   </aff-alternatives>
   <volume>20</volume>
   <issue>5</issue>
   <history>
    <date date-type="received" iso-8601-date="2021-10-29T12:47:57+03:00">
     <day>29</day>
     <month>10</month>
     <year>2021</year>
    </date>
   </history>
   <self-uri xlink:href="https://rjes.ru/en/nauka/article/46535/view">https://rjes.ru/en/nauka/article/46535/view</self-uri>
   <abstract xml:lang="ru">
    <p>The Northwest manganese mineralization comprises of supergene ores developed in a weathering crust of the Neoarchean manganiferous dolostones of the Transvaal Supergroup. These are near-surface accumulation of manganese wad and nodules. The manganese wad is preserved in a typical karstic structures on top of the weathered manganiferous dolostones within the Waterval Saprolite. The saprolite is in turn overlain with a sharp erosional contact by West-wits alluvium hosting manganese nodules. Ore formation is attributed to in-situ surficial weathering, partial dissolution and leaching of ore substances from the manganiferous dolostones. These combined processes led to the release of Mn and Fe rich colloidal particles into the overlying water column of the depository, which later precipitated as manganese nodules upon interaction with alluvial sediments which acted as substrates and centers of accretion. This study presents results on the mineralogy, geochemical constituents and geological occurrence of the ore mineralization. Mineralogical studies indicated the occurrence of romanechite, cryptomelane and galaxite as predominant manganese oxide phases, and pyrolusite and vernadite occurring in minute quantities. Geochemical and mineralogical data anomalies obtained in this study were used to develop a genetic classification of the ore deposit. On the basis of trace element geochemistry applied in this study coupled with studies of mineralogical and diagenetic features of the samples, different manganese classification schemes were adopted and inferences were made from the data interpretation which indicated supergene and hydrogenetic nature of the ore mineralization suggesting precipitation of ore substances from the weathered Mn colloids in a supergene zone.</p>
   </abstract>
   <trans-abstract xml:lang="en">
    <p>The Northwest manganese mineralization comprises of supergene ores developed in a weathering crust of the Neoarchean manganiferous dolostones of the Transvaal Supergroup. These are near-surface accumulation of manganese wad and nodules. The manganese wad is preserved in a typical karstic structures on top of the weathered manganiferous dolostones within the Waterval Saprolite. The saprolite is in turn overlain with a sharp erosional contact by West-wits alluvium hosting manganese nodules. Ore formation is attributed to in-situ surficial weathering, partial dissolution and leaching of ore substances from the manganiferous dolostones. These combined processes led to the release of Mn and Fe rich colloidal particles into the overlying water column of the depository, which later precipitated as manganese nodules upon interaction with alluvial sediments which acted as substrates and centers of accretion. This study presents results on the mineralogy, geochemical constituents and geological occurrence of the ore mineralization. Mineralogical studies indicated the occurrence of romanechite, cryptomelane and galaxite as predominant manganese oxide phases, and pyrolusite and vernadite occurring in minute quantities. Geochemical and mineralogical data anomalies obtained in this study were used to develop a genetic classification of the ore deposit. On the basis of trace element geochemistry applied in this study coupled with studies of mineralogical and diagenetic features of the samples, different manganese classification schemes were adopted and inferences were made from the data interpretation which indicated supergene and hydrogenetic nature of the ore mineralization suggesting precipitation of ore substances from the weathered Mn colloids in a supergene zone.</p>
   </trans-abstract>
   <kwd-group xml:lang="ru">
    <kwd>Supergene manganese ores</kwd>
    <kwd>mineralogy</kwd>
    <kwd>geochemistry</kwd>
    <kwd>ore occurrence</kwd>
    <kwd>romanechite</kwd>
    <kwd>General Mine</kwd>
    <kwd>weathering crust</kwd>
   </kwd-group>
   <kwd-group xml:lang="en">
    <kwd>Supergene manganese ores</kwd>
    <kwd>mineralogy</kwd>
    <kwd>geochemistry</kwd>
    <kwd>ore occurrence</kwd>
    <kwd>romanechite</kwd>
    <kwd>General Mine</kwd>
    <kwd>weathering crust</kwd>
   </kwd-group>
   <funding-group>
    <funding-statement xml:lang="en">The first author would like to thank the South African Ministry of Education for the provision of research funding which covered the field work and some of the laboratory tests which were carried out for the research. The Ministry of Education in the Russian Federation is acknowledged for funding the registration and stay in the Saint Petersburg Mining University.</funding-statement>
   </funding-group>
  </article-meta>
 </front>
 <body>
  <p></p>
 </body>
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