Water Content and Pb Concentrations in the Bottom Sediments Of The Gdansk Deep (South-Eastern Baltic Sea) According to the Portable X-Ray Fluorescence Analyzer Olympus Vanta C

D. Laskina; E. V. Dorokhova; Yu. Koroleva

doi:10.2205/2024ES000879

VAK Russia 1.6 UDC 55 CSCSTI 37.01 Russian Classification of Professions by Education 05.00.00 Russian Library and Bibliographic Classification 26 Russian Trade and Bibliographic Classification 63 BISAC SCI UDC 550.34 UDC 550.383 CSCSTI 37.15 CSCSTI 37.25 CSCSTI 37.31 CSCSTI 38.01 CSCSTI 36.00 CSCSTI 37.00 CSCSTI 38.00 CSCSTI 39.00 CSCSTI 52.00

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WATER CONTENT AND PB CONCENTRATIONS IN THE BOTTOM SEDIMENTS OF THE GDANSK DEEP (SOUTH-EASTERN BALTIC SEA) ACCORDING TO THE PORTABLE X-RAY FLUORESCENCE ANALYZER OLYMPUS VANTA C Water Content and Pb Concentrations in the Bottom Sediments Of The Gdansk Deep (South-Eastern Baltic Sea) According to the Portable X-Ray Fluorescence Analyzer Olympus Vanta C

АА Аа

Published in Russian Journal of Earth Sciences · Volume 24, Issue 3 · Pages 1–17 · Rubric: ORIGINAL ARTICLES

DOI: https://doi.org/10.2205/2024ES000879 · EDN: XVPFOK

Received: 10.06.2023 Accepted: 12.07.2024 Published: 12.07.2024

Authors

D. Laskina

ORCID

E. V. Dorokhova

ORCID

Yu. Koroleva

ORCID

D. Laskina

Immanuel Kant Baltic Federal University Kaliningrad

P.P.Shirshov Institute of Oceanology of the Russian Academy of Science Moscow

ORCID

E. V. Dorokhova

P.P.Shirshov Institute of Oceanology of the Russian Academy of Science Moscow

Immanuel Kant Baltic Federal University Kaliningrad

ORCID

Yu. Koroleva

Immanuel Kant Baltic Federal University Kaliningrad

ORCID

ABSTRACT

This work describes a method for determining the water content in sediments from the Gulf of Gdansk of the Baltic Sea, which is based on the analysis of spectral data obtained using the portable X-ray fluorescence analyzer (XRF) Olympus Vanta C. The water content calculated from the XRF spectral data showed a high correlation (𝑟 = 0.95) with those measured using the conventional method of drying to constant mass. This allows the conversion between the results obtained using the portable XRF analyzer on bulk sediments to those obtained on dried sediments. Comparison of the converted data from the portable analyzer with the results of element composition analysis performed on dried homogenized samples using the wavelength-dispersive XRF analyzer Spectroscan-Max-G and atomic absorption spectrophotometer Varian AA240FS showed high correlation coefficients for Mn, Ca, K, Zn, Pb, As and low coefficients for Fe, Co, Ti, Ni, Cu and Sr. The results of the analysis using the portable XRF spectrometer, converted to dry weight of the sediment, were used to study the distribution of Pb concentrations in the sediments of the Gulf of Gdansk. An increase in Pb content up to 60 ppm was observed in the upper part of sediment cover. This increase is likely associated with the intensification of anthropogenic activities in AD 1 and AD 1200. Maximum lead concentrations up to 124 ppm were found in near-surface sediments, likely related to the period of industrialization in the 1970s.

KEYWORDS

sediment cores, Spectroscan-Maks-G, coherent and incoherent scattering, anthropogenic source of lead input

Funding

The authors thank Professor J. F. Boyle for assistance in determining the humidity from the scattering spectra, D. G. Borisov for fruitful discussion of the results and stylistic corrections of the text, and E. P. Zholinskaya for performing chemical analyses on AAS. We also thank two anonymous reviewers, whose comments allowed us to significantly improve the article. The study of humidity and comparison of element content values was carried out within the framework of the state assignment of the IO RAS (topic No. FMWE-2024-0025), the study of lead distribution in bottom sediment cores was carried out within the framework of the RSF grant No. 22-17-00170, https://rscf.ru/project/22-17-00170/.

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GOST

Laskina D. N., Dorokhova E. V., Koroleva Y. V. Water Content and Pb Concentrations in the Bottom Sediments Of The Gdansk Deep (South-Eastern Baltic Sea) According to the Portable X-Ray Fluorescence Analyzer Olympus Vanta C // Russian Journal of Earth Sciences. 2023. no. 3. pp. 1-17. DOI: https://doi.org/10.2205/2024ES000879. EDN: XVPFOK. (Date of access 22.09.2026).

MLA

D. Laskina, Dorokhova E. V., Koroleva Y. V.. "Water Content and Pb Concentrations in the Bottom Sediments Of The Gdansk Deep (South-Eastern Baltic Sea) According to the Portable X-Ray Fluorescence Analyzer Olympus Vanta C." Russian Journal of Earth Sciences 24.3 (2023): 1-17. DOI: https://doi.org/10.2205/2024ES000879. EDN: XVPFOK.

APA

Laskina D. N., Dorokhova E. V., Koroleva Y. V. (2023). Water Content and Pb Concentrations in the Bottom Sediments Of The Gdansk Deep (South-Eastern Baltic Sea) According to the Portable X-Ray Fluorescence Analyzer Olympus Vanta C. Russian Journal of Earth Sciences, 24(3), 1-17. https://doi.org/10.2205/2024ES000879 EDN: XVPFOK.

Chicago

D. Laskina, Dorokhova E. V., Koroleva Y. V.. "Water Content and Pb Concentrations in the Bottom Sediments Of The Gdansk Deep (South-Eastern Baltic Sea) According to the Portable X-Ray Fluorescence Analyzer Olympus Vanta C." Russian Journal of Earth Sciences 24, no. 3 (2023): 1-17. https://doi.org/10.2205/2024ES000879. EDN: XVPFOK.

WIKI

{{cite journal | author = Laskina D. N., Dorokhova E. V., Koroleva Y. V. | title = Water Content and Pb Concentrations in the Bottom Sediments Of The Gdansk Deep (South-Eastern Baltic Sea) According to the Portable X-Ray Fluorescence Analyzer Olympus Vanta C | journal = Russian Journal of Earth Sciences | year = 2023 | volume = 24 | issue = 3 | pages = 1-17 | doi = 10.2205/2024ES000879 }} EDN: XVPFOK

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