KINETICS OF CRYSTALLIZATION AND MELTING OF HYDRATE--PARAFFINS AND PREDICTION OF THEIR FORMATION IN OIL WELLS OF NEPA-BOTUOBIAN ANTECLISE (EASTERN SIBERIA)
Аннотация и ключевые слова
Аннотация (русский):
The study is focused on the results of kinetic analysis of processes of crystallization and melting of hydrates synthesized in model systems ``natural gas + water'' and ``natural gas + asphaltene-resin-paraffin deposits (ARPD) + water''. Synthesis and decomposition of hydrates in the systems under investigation were carried out in a calorimetric cell of differential scanning calorimetry (DSC). The kinetics description of processes is carried out applying the Avrami equation. Based on the obtained data, the rate constants, order of reactions, and half-life time periods of formation in gas and oil wells has shown that $P$, $T$-conditions hydrate-paraffin formation correspond to the actual thermobaric conditions of several oil and gas fields located in the permafrost area.

Ключевые слова:
Gas and hydrate systems, Biogeochemical kinetics, reaction modeling, Clathrate
Текст
Текст произведения (PDF): Читать Скачать
Список литературы

1. Akhfash, M., Aman, Z. M., Ahn, S. Y., Johns, M. L., May, E. F. Gas hydrate plug formation in partially-dispersed water-oil systems, // Chem. Eng. Sci., 2016. - v. 140 - p. 337.

2. Avrami, M. Kinetics of Phase Change, // J. Chem. Phys., 1939. - v. 7 - p. 1103.

3. Blanc, C., Tournier-Lasserve, J. Controlling hydrates in high-pressure flowlines, // World Oil, 1990. - v. 211 - no. 5 - p. 1103.

4. Byk, S.., Makogon, Yu., Fomina, V. Gazovyye Gidraty - Khimiya: Moscow., 1980.

5. Dalmazzone, D., Hamed, N., Dalmazzone, C. DSC Measurements and modeling of the kinetics of methane hydrate formation in water-in-oil emulsion, // Chem. Eng. Sci., 2009. - v. 64 - no. 9 - p. 2020.

6. Dalmazzone, D., Hamed, N., Dalmazzone, C., Rosseau, L. Application of high pressure DSC to the kinetics of formation of methane hydrate in water-in-oil emulsion, // J. Therm. Anal. Calorim., 2006. - v. 85 - p. 361.

7. Davies, S. R., et al. Predicting hydrate-plug formation in a subsea tieback, // SPE Prod. Oper., 2009. - v. 24 - p. 573.

8. Delgado-Linares, J., Majid Ahmad, A., Sloan, E., Koh, C., Sum, A. K. Model water-in-oil emulsions for gas hydrate studies in oil continuous systems, // Energy Fuels, 2013. - v. 27 - no. 8 - p. 4564.

9. Elemanov, B. D., Gershtansky, O. S. Oslozhneniya Pri Dobyche Nefti - Moscow: Nauka., 2007.

10. Greaves, D., Boxall, J., Mulligan, J., Sloan, E. D., Koh, C. A. Hydrate formation from high water content-crude oil emulsions, // Chem. Eng. Sci., 2008. - v. 63 - p. 4570.

11. Gupta, A., Lachance, J., Sloan, E. D., Koh, C. A. Measurements of methane hydrate heat of dissociation using high pressure Differential Scanning Calorimetry, // Chem. Eng. Sci., 2008. - v. 63 - p. 5848.

12. Ivanova, I. K., Semenov, M. E., Koryakina, V. V., Shits, E. Yu., Rozhin, I. I. Investigation of natural gas hydrates formation/decomposition processes in systems consisting of ``commercial asphaltene-resin-paraffin deposits and water'', // Russian Journal of Applied Chemistry, 2015. - v. 88 - no. 6 - p. 941.

13. Ivanova, I. K., Shitz, E. Yu. Using of the gas condensate for fighting with organic deposits in the condition of abnormally low reservoir temperatures, // Oil Industry, 2009. - v. 12 - p. 99.

14. Ivanova, I. K., Semenov, M. E., Rozhin, I. I. Synthesis and phase transformations of natural gas hydrates of Srednevilyuiskoe field, // Russian Journal of Applied Chemistry, 2014. - v. 87 - no. 8 - p. 1094.

15. Istomin, V. A. Preduprezhdeniye i Likvidatsiya Gazovykh Gidratov v Sistemakh Sbora i Promyslovoy Obrabotki Gaza i Nefti - Moscow: Vsesoyuz. Nauch.-Issled. In-t Ekonomiki Gazovoy Promyshlennosti., 1990.

16. Kalacheva, L. P., Fedorova, A. F., Shitz, E. Y., Rozhin, I. I. Characteristic patterns in natural gas hydrate composition and structure in deposits of Yakutia, // SOCAR Proceedings, 2015. - v. 3 - no. 3 - p. 4.

17. Kashircev, V. A. Organicheskaya Geokhimiya Naftidov Vostoka Sibirskoy Platformi - Yakutsk: YaF Izd-vo SO RAN., 2003.

18. Koh, C. A., Sum, A. K., Sloan, E. D. State of the art: Natural gas hydrates as a natural resource, // Journal of Natural Gas Science and Engineering, 2012. - v. 8 - p. 132.

19. Kuo, M. C., Huang, J. C., Chen, M. Non-isothermal crystallization kinetic behavior of alumina nanoparticle filled poly(ether ether ketone), // Materials Chemistry and Physics, 2006. - v. 99 - no. 2-3 - p. 258.

20. Makogon, Yu. F. Gazovyye Gidraty, Preduprezhdeniye Ikh Obrazovaniya i Ispol'zovaniya - Moscow: Nedra., 1985.

21. Rozovskiy, A. Ya. Kinetika Topokhimicheskikh Reaktsiy - Moscow: Khimiya., 1974.

22. Rozhin, I. I. Termodinamicheskiye effekty v matematicheskikh modelyakh dobychi prirodnogo gaza v severnykh regionakh - Novosibirsk: IT SO RAN., 2015.

23. Sayakhov, F. L., Bagautdinov, N. Ya. Electrothermal Methods of Action on Hydrate-Paraffin Sediments - Moscow: Nedra-Business., 2003.

24. Semenov, M. E., et al. DSC and thermal imaging studies of methane hydrate formation and dissociation in water emulsions in crude oils, // J. Therm. Anal. Calorim., 2015. - v. 119 - no. 1 - p. 757.

25. Sloan, E. D. Hydrate Engineering (Ed. by J. B. Bloys) - Texas: Richardson., 2000.

26. Sloan, E. D. Natural Gas Hydrates in Flow Assurance - GPP: Elsevier., 2011.

27. Sloan, E. D., Koh, C. A. Clathrate Hydrates of Natural Gases, 3rd edition - London, New-York: CRC Press, Boca Rator., 2008.

28. Stoporev, A. S., Manakov, A. Y., Aladko, E. Y., Altunina, L. K., Bogoslovskii, A. V., Strelets, L. A. Dependence of the rate of formation and the $P-T$ stability field of methane hydrate suspensions in crude oils upon oil composition, // Petroleum Chemistry, 2014. - v. 54 - no. 3 - p. 171.

29. Talatori, S., Barth, T. Rate of hydrate formation in crude oil/gas/water emulsions with different water cuts, // Journal of Petroleum Science and Engineering, 2012. - v. 80 - p. 32.

30. Talatori, S., Fotland, P., Barth, T. Kinetics of hydrate formation in a water-oil-gas system - Canada: Vancouver., 2008.

31. Turner, D., Miller, K., Sloan, E. Methane hydrate formation and an inward growing shell model in water-in-oil dispersions, // Chem. Eng. Sci., 2009. - v. 64 - p. 3996.

32. Zalivin, V. G., Vakhromeyev, A. G. Avariynyye Situatsii v Burenii - Irkutsk: Izd-vo IRNITU., 2016.

33. Zi, M., Chen, D., Ji, H., Wu, G. Effects of asphaltenes on the formation and decomposition of methane hydrate: Amolecular dynamics study, // Energy Fuels, 2016. - v. 30 - no. 7 - p. 5643.

Войти или Создать
* Забыли пароль?